diff --git "a/\347\204\241\346\251\237\345\214\226\345\255\246/children/appendix.tex" "b/\347\204\241\346\251\237\345\214\226\345\255\246/children/appendix.tex" index 03af329..2b40d1a 100644 --- "a/\347\204\241\346\251\237\345\214\226\345\255\246/children/appendix.tex" +++ "b/\347\204\241\346\251\237\345\214\226\345\255\246/children/appendix.tex" @@ -112,7 +112,7 @@ \part{APPENDIX} \end{longtable} \newpage \section{金属イオンの系統分離} - \begin{tikzpicture}[process/.style={right, draw=black, rectangle, semithick, rounded corners=3pt, dash dot},arrow/.style={-Stealth,thick},extract/.style={right, draw=black, rectangle, semithick, rounded corners=3pt}] + \begin{tikzpicture}[process/.style={right, draw=black, rectangle, semithick, rounded corners=3pt, dash dot},arrow/.style={-Stealth,thick},extract/.style={left, draw=black, rectangle, semithick, rounded corners=3pt}] \node[below right, draw=black, rectangle, rounded corners=4pt, line width=1pt, inner sep=4pt, outer sep=0pt] (begin) {金属イオンの混合溶液}; \node[below right, draw=black, rectangle, rounded corners=4pt, line width=1pt, inner sep=4pt, outer sep=0pt] (end) at (0,-22) {\hl{\ce{K^+}},\hl{\ce{Na^+}},\hl{\ce{Mg^+}}}; \coordinate (start point) at ($(begin.south west)!0.15!(begin.south east)$); @@ -123,20 +123,17 @@ \part{APPENDIX} \coordinate (extract4) at ([yshift=-16cm]start point); \coordinate (extract5) at ([yshift=-20.5cm]start point); - \node[process] (1st) at ([xshift=1cm]$(start point)!0.5!(extract1)$){ - \begin{minipage}{3cm} - \hl{希塩酸}\\ - $\Rightarrow$\hl{\ce{Cl-}}(\hl{酸}性) - \end{minipage} + \node[process] (1st) at ([xshift=1cm]$(start point)!0.33!(extract1)$){ + \hl{希塩酸}$\Rightarrow$\hl{\ce{Cl-}}(\hl{酸}性) }; \node[process] (2nd) at ([xshift=1cm]$(extract1)!0.5!(extract2)$){ - \begin{minipage}{3cm} + \begin{minipage}{4.5cm} \hl{硫化水素}\\ $\Rightarrow$\hl{\ce{S^2-}}(\hl{酸}性) \end{minipage} }; \node[process] (3rd) at ([xshift=1cm]$(extract2)!0.5!(extract3)$){ - \begin{minipage}{7.5cm} + \begin{minipage}{8cm} \begin{enumerate} \setlength{\leftskip}{-13pt} \item \hl{煮沸}する$\Rightarrow$\hl{硫化水素}を除去 @@ -149,7 +146,7 @@ \part{APPENDIX} \end{minipage} }; \node[process] (4th) at ([xshift=1cm]$(extract3)!0.5!(extract4)$){ - \begin{minipage}{3.5cm} + \begin{minipage}{4cm} \hl{硫化水素}を加える\\ \hl{\ce{S^2-}}(\hl{塩基}性) \end{minipage} @@ -173,7 +170,7 @@ \part{APPENDIX} \draw[arrow] (4th.west) -- ($(start point)!(4th.west)!(end point)$); \draw[arrow] (5th.west) -- ($(start point)!(5th.west)!(end point)$); - \node[extract] (group1) at ([xshift=5cm]extract1) { + \node[extract] (group1) at ([xshift=15cm]extract1) { \begin{tabular}{ll|ll} \hl{\ce{AgCl}}&\hl{白}色&\hl{\ce{Hg2Cl2}}&\hl{白}色\\ \hl{\ce{PbCl2}}&\hl{白}色&& @@ -193,14 +190,14 @@ \part{APPENDIX} \draw[arrow] (group1-3.west) -- ($(group1-start point)!(group1-3.west)!(group1-end point)$); \draw[arrow] ($(group1-start point)!(group1-4.east)!(group1-end point)$) -- (group1-4.east); - \node[extract] (group2) at ([xshift=5cm]extract2) { + \node[extract] (group2) at ([xshift=11cm]extract2) { \begin{tabular}{ll|ll} \hl{\ce{HgS}}&\hl{黒}色&\hl{\ce{CuS}}&\hl{黒}色\\ \hl{\ce{SnS}}&\hl{褐}色&\hl{\ce{CdS}}&\hl{黄}色\\ (\hl{\ce{PbCl2}}&\hl{黒}色)&& \end{tabular} }; - \node[extract, above] (group2-result) at ([yshift=-4cm]$(group2.south)!1.3!(group2.south east)$){\hl{\ce{Cu^2+}}}; + \node[extract, above] (group2-result) at ([yshift=-4cm,xshift=3cm]group2.south east){\hl{\ce{Cu^2+}}}; \coordinate (group2-end point) at (group2-result.north); \coordinate (group2-start point) at ([yshift=-0.5cm]$(group2.west)!(group2-end point)!(group2.east)$); \draw[arrow] (group2.east) -| (group2-end point); @@ -218,7 +215,7 @@ \part{APPENDIX} \draw[arrow] (group2-5.west) -- ($(group2-start point)!(group2-5.west)!(group2-end point)$); \draw[arrow] ($(group2-start point)!(group2-6.east)!(group2-end point)$) -- (group2-6.east); - \node[extract] (group3) at ([xshift=4cm]extract3) { + \node[extract] (group3) at ([xshift=12cm]extract3) { \begin{tabular}{ll|ll} \hl{\ce{Fe(OH)3}}&\hl{淡緑}色&\hl{\ce{Cr(OH)3}}&\hl{黒}色\\ \hl{\ce{Al(OH)3}}&\hl{白}色&& @@ -227,14 +224,14 @@ \part{APPENDIX} \node[process] (group3-1) at ([xshift=1cm]group3.east){沈澱の色}; \draw[arrow] (group3-1.west) -- ($(group3.north east)!(group3-1.west)!(group3.south east)$); - \node[extract] (group4) at ([xshift=4cm]extract4) { + \node[extract] (group4) at ([xshift=11cm]extract4) { \begin{tabular}{ll|ll} \hl{\ce{NiS}}&\hl{黒}色&\hl{\ce{CoS}}&\hl{黒}色\\ \hl{\ce{ZnS}}&\hl{白}色&\hl{\ce{MnS}}&\hl{淡黄}色\\ \end{tabular} }; \node[process] (group4-1) at ([xshift=1cm]group4.east){ - \begin{minipage}{5.2cm} + \begin{minipage}{6.2cm} 沈澱の色・元の混合溶液の色\\ \begin{tabular}{l|l} \ce{Ni^2+}\hl{緑}色&\ce{Co^2+}\hl{淡赤}色 @@ -242,7 +239,7 @@ \part{APPENDIX} \end{minipage}}; \draw[arrow] (group4-1.west) -- ($(group4.north east)!(group4-1.west)!(group4.south east)$); - \node[extract] (group5) at ([xshift=4cm]extract5) { + \node[extract] (group5) at ([xshift=11cm]extract5) { \begin{tabular}{ll|ll} \hl{\ce{CaCO3}}&\hl{白}色&\hl{\ce{BaCO3}}&\hl{白}色\\ \hl{\ce{StCO3}}&\hl{白}色&& diff --git "a/\347\204\241\346\251\237\345\214\226\345\255\246/children/transition.tex" "b/\347\204\241\346\251\237\345\214\226\345\255\246/children/transition.tex" index 3eada9e..82536be 100644 --- "a/\347\204\241\346\251\237\345\214\226\345\255\246/children/transition.tex" +++ "b/\347\204\241\346\251\237\345\214\226\345\255\246/children/transition.tex" @@ -3,7 +3,6 @@ \part{遷移元素} d軌道・f軌道(内殻)の秋に電子が入っていき、最外殻電子の数は\hl{1か2}\\ (\hl{ランタノイド}・\hl{アクチノイド}:f軌道に入っていく過程)\\ 同族元素だけでなく、同周期元素も性質が似ている。 - \section{性質} \begin{itemize} \item 単体は密度が\hl{大き}く、融点が\hl{高い}金属 \item d軌道の一部の電子も価電子 diff --git "a/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.pdf" "b/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.pdf" index 3eb1b4a..d31d64e 100644 Binary files "a/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.pdf" and "b/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.pdf" differ diff --git "a/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.tex" "b/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.tex" index 882b12e..cd45741 100755 --- "a/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.tex" +++ "b/\347\204\241\346\251\237\345\214\226\345\255\246/inorganic-chemistry.tex" @@ -33,7 +33,7 @@ line width=.5pt, inner sep=2pt, outer sep=0pt ] (num){\addtocounter{answer}{1}\arabic{answer}}; \node [right, inner sep=1pt, outer sep=0pt] (text) at (num.east){#1}; - \draw [line width=.5pt, outer sep=0pt] (num.south)--($(text.base east)-(num.base west)+(num.south)+(-5pt,0)$); + %\draw [line width=.5pt, outer sep=0pt] (num.south)--($(text.base east)-(num.base west)+(num.south)+(-5pt,0)$); \end{tikzpicture}% } \newcounter{answer} @@ -86,10 +86,11 @@ \hypertarget{top}{\tableofcontents} \onecolumn -%\include{children/non‐metallic} -%\include{children/representative} -%\include{children/transition} +\include{children/non‐metallic} +\include{children/representative} +\include{children/transition} \renewcommand{\thesection}{\Alph{section}} +\setcounter{answer}{0} \setcounter{section}{0} \include{children/appendix} \end{document} \ No newline at end of file